Abstract

Polarization labelling spectroscopy is applied to study the excited E 1Σ + state of NaLi in the energy range 26 500–28 000 cm −1 above the bottom of the ground state. The potential curve of the E state is constructed using the Inverted Perturbation Approach method. The values of T e, ω e and R e are found to be 26 474.82(4), 180.3(2) cm −1 and 3.343(1) Å, respectively.

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