Abstract

The paint stratigraphy of the two clock faces from the tower clock of the Government Palace in Helsinki (Finland) was analysed in order to determine their original colour before restoration works. Paint cross-section samples from both clock faces were analysed by confocal Raman microscopy and scanning electron microscopy coupled to an energy dispersive X-ray spectrometer (SEM–EDS). The results revealed the complex superimposition of paint layers applied over the original black colour. FTIR/ATR analyses proved that the original paint was prepared with linseed oil-resin media. Most likely not all of the different layer colours were visible. Some of the layers were likely to have been a primer or for rust protection.

Highlights

  • There are a wide variety of techniques available for the analysis of items of cultural heritage

  • The SEM–EDS analysis revealed the numerous layers of materials used in several restoration works

  • This study is an example of how science and technology can be useful in the field of cultural heritage

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Summary

Introduction

There are a wide variety of techniques available for the analysis of items of cultural heritage. The use of traditional techniques to investigate valuable artworks is sometimes impossible, since profuse sampling procedures are forbidden. The versatility and adaptability of portable/handheld Raman spectrometers have been demonstrated by studies carried out on rock paintings in caves and rockshelters [2,3,4], mural paintings [5], plasterworks [6] or valuable collections in museums [7]. Whenever cultural heritage samples are to be analysed, non-destructive mobile instrumentation provides a unique opportunity to collect in situ data and ensure the integrity of the artwork. Nowadays it is possible to say that the results obtained by in situ analysis are of the same quality as those obtained by laboratory instruments [12, 13]

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