Abstract
ABSTRACTCharge transfer (CT) complexes formed between 2-amino-4-methylpyridine as electron donor, chloranilic acid as electron acceptor was investigated spectrophotometrically in acetonitrile (AN), methanol (MeOH) and binary mixture of acetonitrile 50% + methanol 50% (MeOH-AN). Minimum–maximum absorbance method has been used for estimating the formation constants of the CT reactions (KCT). Job’s method of continuous variation and photometric titration studies were used to detect the stoichiometric ratios of the formed complexes, and they showed that 1:1 complexes were produced. The molar extinction coefficient (e), oscillator strength (f), dipole moment (l), CT energy (ECT), ionisation potential (IP) and the dissociation energy (W) of the formed complexes were estimated; they reached acceptable values suggesting the stability of the formed CT complexes. The solid CT complexes were synthesised and characterised by elemental analyses, 1H NMR and FTIR spectroscopies where the formed complexes included proton and electron transfer.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call