Spectrophotometric determination of lead with N-hydroxy-N,N′-diphenylbenzamidine and diphenylcarbazone in airborne dust particulates and soil

Abstract

A simple, selective and sensitive method for the spectrophotometric determination of lead in airborne dust particulate and soil samples is described. The method is based on the selective extraction of lead at pH 10.0 ± 0.2 with N-hydroxy-N,N′-diphenylbenzamidine (HDPBA). The yellow PbII–HDPBA complex shows maximum absorbance at 410 nm with a molar absorptivity of 1.6 × 104 l mol–1 cm–1. The sensitivity of the method is further increased by the addition of a methanolic solution of diphenylcarbazone (DPCZO) to the extract. The pink PbII–HDPBA/DPCZO complex has a molar absorptivity of 7.2 × 104 l mol–1 cm–1 at λmax = 525 nm. The detection limit of the method is 4 ng ml–1 in the organic phase and the Sandell’s sensitivity of the method is 0.0015 µg cm–2. The relative standard deviation for 10 replicate measurements of Pb at a level of 1.0 µg ml–1 is 1.5%. The method has been successfully applied to the determination of PbII in airborne dust particulates and soil samples.