Spectral responsivity and quantum efficiency of n-ZnO/p-Si photodiode fully isolated by ion-beam treatment

Abstract

We report on the fabrication of a heterojunction photodiode for the visible range that consists of a transparent insulating ZnO overlayer and a transparent semiconducting n-ZnO layer on p-Si. For device isolation, we implanted Si+ ions into the n-ZnO layer. We have obtained a wide-range spectral responsivity curve for our isolated photodiodes, which showed a maximum quantum efficiency of 70% at 650 nm and a minimum of 10% at 420 nm. However, they exhibited an efficiency drop at 380 nm in the near-ultraviolet because the ZnO layers absorbed the photons of higher energy before they reached p-Si. The ion-beam-induced isolation considerably reduced dark leakage currents in our devices when the dose of Si ions was as high as 5×1015 cm−2.