Abstract
Tin(IV) chloride derivatives of nickel(II) thiocarbohydrazones were obtained by reacting tin(IV) chloride with nickel(II) thiocarbohydrazones in chloroform medium. All the complexes are greenish coloured solids and appear to be non-electrolytes in DMF. Elemental analyses conform to the 1:1 stoichiometry. Magnetic, electronic and IR spectral information suggest that square planar nickel(II) thiocarbohydrazones have changed their configuration to octahedral as a result of reaction with tin (IV) chloride.
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