Abstract

Specific features of the structures of mononuclear octahedral rhenium(V) oxo complexes with oxygen atoms of neutral ligands OER3 (E = P, As; R3 = Ph3, PhEt2) trans to the multiply bonded oxo ligands have been considered. The complexes contain halide ligands, as well as organic monoand bidentate ligands, in the equatorial plane. The Re–O(OER3)trans bonds are elongated owing to the structural manifestation of the trans influence of multiply bonded oxo ligands.

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