Year-end Sale % OFF 
Abstract
Some structural features of mononuclear octahedral rhenium(V) oxo complexes with oxygen atoms of propoxo ligands O(Pr-iso)− in trans-positions to multiply bonded oxo ligands are considered. The complexes contain monodentate inorganic or organic ligands or bi- and tetradentate organic ligands in the equatorial plane. Re-O(OPr) trans bonds, as well as the other bonds with (ORalkoxo) trans alkoxo ligands (R = Me, Et), are considerably shortened, instead of being elongated, due to the structural manifestation of the trans-effect of multiply bonded oxo ligands. This is explained by that these Re-O(ORalkoxo) bonds also have an increased multiplicity; that is, d 2 rhenium(V) monooxomonoalkoxo complexes should be considered as pseudo-dioxo Re(=O)(=ORalkoxo) compounds.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
