Spatiotemporal distribution of polycyclic aromatic hydrocarbons in sediments of a typical river located in the Loess Plateau, China: Influence of human activities and land-use changes

Abstract

The Loess Plateau, as the key energy base of China, has sensitive responses to the global changes, and receives polycyclic aromatic hydrocarbons (PAHs) from anthropogenic activities. However, understanding how anthropogenic and climate factors affect synergistically the PAHs distribution in this vulnerable ecological environment is deficient. Here the spatiotemporal distribution of PAHs in sediments from a typical river of the Loess Plateau were investigated. The PAHs were mainly from coal combustion in the range of 194–514 ng g−1, and their concentrations were generally higher in normal season than wet season as the dilution effect of high river discharge and strong precipitation. The interactive effects of land-use and precipitation showed PAHs enriched in forest-grass land were transferred into rivers through surface and subsurface runoff during light rainfall, resulting in the increase of the PAHs concentrations in river sediments. In contrast, large precipitation in wet season would obscure any spatial variations. In addition, human activities, especially energy production, directly enhanced PAHs accumulation in river sediments due to the emission from the production processing of oil and coal, and indirectly influenced the PAHs by impacting the per capita GDP. These findings had important implications for the management and prediction of PAH accumulation.