Spatially resolved broadband absorption spectroscopy measurements of temperature and multiple species (NH, OH, NO, and NH[formula omitted]) in atmospheric-pressure premixed ammonia/methane/air flames

Abstract

The temperature and multi-species concentration distributions, including NH, OH, NO, and NH3, are of great importance to the research on ammonia/methane combustion mechanisms. However, there is scarce research simultaneously measuring these parameters in atmospheric-pressure ammonia/methane flames. In this work, we proposed a measurement method based on the ultraviolet broadband absorption spectroscopy (BAS) to realize the simultaneous measurement of temperature and multiple species concentrations for the first time (absolute concentrations for OH, NH, and NO, and relative concentrations for NH3). Due to the strong absorption of the electronic transitions in the ultraviolet range, the proposed method offers low detection limits for concentration measurements. Taking NH radicals as an example, the detection limit is as low as 31 ppb at 1700 K. High sensitivity for temperature measurements is also achieved due to the multi-line spectra of OH broadband absorption. Moreover, a fitting strategy was proposed to separate the NO and NH3 spectra near 225 nm, enabling a simultaneous determination of both species. We established an optical system based on the proposed BAS method with a spatial resolution of approximately 0.1 mm to perform spatially resolved measurements of temperature and multiple species on atmospheric ammonia/methane/air flames. The ammonia/methane flames were investigated at different equivalence ratios (0.9, 1.0, and 1.1) and different ammonia mole fractions in fuels (10%, 30%, and 50%). As investigated, NH and NH3 concentrations increased linearly with increasing ammonia mole fractions, while OH and NO concentrations decreased in similar trends with increasing equivalence ratios. The experimentally measured temperature and multi-species concentrations were compared with computational fluid dynamics (CFD) simulations using the mechanism of the CRECK modeling group. Good agreements were achieved in absolute values, spatial profiles, and variations with equivalence ratios and ammonia mole fractions.