Spatial and temporal coarse graining for dispersion in randomly packed spheres.

Abstract

The propagator for molecular displacements P(zeta, t) and its first three cumulants were measured for Stokes flow in monodisperse bead packs with different sphere sizes d and molecular diffusion coefficients D(m). We systematically varied the normalized mean displacement <zeta>/d and diffusion length L(D)=sqrt[2D(m)t]/d. The experimental results map onto each other with this scaling. For L(D)/d<0.2 the propagator remains non-Gaussian, and thus an advection diffusion equation is not obeyed, for mean displacements measured up to <zeta>>10d. A Gaussian shape is approached for large mean displacements when L(D)>0.3d.