Sparse ab initio x-ray transmission spectrotomography for nanoscopic compositional analysis of functional materials.

Zirui Gao,Michal Odstrcil,Dario Ferreira Sanchez,Frank Krumeich,Sebastian Böcklein,Marco Stampanoni,Andreas Menzel,Johannes Ihli,Manuel Guizar-Sicairos,Jeroen Anton Van Bokhoven,Mirko Holler,Dennis Palagin,Gerhard Mestl

doi:10.1126/sciadv.abf6971

Abstract

The performance of functional materials is either driven or limited by nanoscopic heterogeneities distributed throughout the material's volume. To better our understanding of these materials, we need characterization tools that allow us to determine the nature and distribution of these heterogeneities in their native geometry in 3D. Here, we introduce a method based on x-ray near-edge spectroscopy, ptychographic x-ray computed nanotomography, and sparsity techniques. The method allows the acquisition of quantitative multimodal tomograms of representative sample volumes at sub-30 nm half-period spatial resolution within practical acquisition times, which enables local structure refinements in complex geometries. To demonstrate the method's capabilities, we investigated the transformation of vanadium phosphorus oxide catalysts with industrial use. We observe changes from the micrometer to the atomic level and the formation of a location-specific defect so far only theorized. These results led to a reevaluation of these catalysts used in the production of plastics.

Highlights

Composition and structure define a material’s functionality [1]
Spectral nanotomography measurements provide a first answer to this question
The detected loss of amorphous vanadium-rich metaphosphate and the increasing absence of secondary vanadium phosphate phases with progressive reactor operation, suggest both features are of minor importance regarding catalyst productivity, which is unexpected given their previous consideration as active site carriers [30, 31]

Summary

Introduction

Composition and structure define a material’s functionality [1]. While we can determine and sometimes predict the relationship between structure and emergent functionality for simple single-component materials with some effort, we frequently face difficulties when dealing with structurally and compositionally more complex materials such as heterogeneous catalysts, energy storage materials, or biominerals [2,3,4]. Functionality is often defined by local heterogeneities in structure and/or composition such as interfaces between two components or selected crystallographic defects, distributed in a larger volume [5, 6]. The distribution of these heterogeneities within frequently hierarchically structured assemblies, spanning multiple length scales, and their interaction with the local environment further guide the material’s functionality or device performance. We face the challenge to provide characterization tools that allow us to determine the nature and distribution of these heterogeneities in their native geometry in three dimensions (3D). This is to better our understanding of current materials and aid the design of next- generation materials

Methods

Results

Conclusion