Abstract
Due to the intense human activities and rapid development of economy, dissolved heavy metals (DHMs) pose a significant threat to urban river ecosystems. Therefore, the distribution, sources, and potential risks of DHMs in the Chaobai River (typical urban river) were investigated via ICP-MS in detail. Results revealed considerable spatial heterogeneity of heavy metals with various concentrations from the upper to lower reach. Principal component analysis (PCA) revealed that V, Ni, As, Mo, and Pb mainly originated from a mixing process of industrial input and natural process, Cr and Cu were mainly derived from urban activities, and Zn was mainly influenced by agriculture activities. Furthermore, land use types within the buffer zone near sampling points were innovatively analyzed, revealing strong correlations between DHMs and regional land use patterns. Monte Carlo simulations were employed to assess the differentiated non-carcinogenic and carcinogenic risks associated with DHMs across four age groups. This study provided scientific references for the sustainable management of urban rivers and aquatic systems in such a megacity region.
Published Version
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