Source identification of polycyclic aromatic hydrocarbons in soil sediments: Application of different methods

Abstract

Polycyclic aromatic hydrocarbons (PAHs) are organic compounds that tend to rapidly associate to particulate organic matter in sediments due to their hydrophobic characteristics, inducing toxic, carcinogens and mutagens effects to many living organisms. The monitoring and identification of the sources of PAHs in sediments is relevant especially because they are the main reservoir and secondary source of contamination of aquatic systems. To identify the sources there are different methods for data treatment that complement each other: evaluation of profiles distribution, source-specific diagnostic ratios of PAHs and principal component analysis (PCA). To demonstrate the applicability of these different methods, concentrations of PAHs from sediments of four Portuguese estuarine systems were used: Ria de Aveiro, Tagus River, Sado River and Ria Formosa, in order to identify the sources.