Source identification and spatial distribution of heavy metals in soil of central urban area of Chongqing, China

Abstract

ABSTRACT To understand the characteristics of heavy metal pollution in soil and identify the source of heavy metals, 342 surface soil samples were collected in Chongqing, China. The contents of 11 heavy metals (i.e., arsenic (As), cadmium (Cd), chromium (Cr), lead (Pb), copper (Cu), zinc (Zn), nickel (Ni), mercury (Hg), antimony (Sb), manganese (Mn), and molybdenum (Mo)) were determined. The Principal Component analysis/absolute Principal component fraction (PCA/APCS) receptor model, the classified regression (CATREG) model, and the hot spot model were employed to analyze the data. The contents of As, Cd, Cr, Pb, Cu, Zn, Ni, Hg, Sb, Mn, and Mo in soil were 5.80, 0.13, 76.56, 25.55, 23.99, 75.58, 30.50, 0.05, 0.64, 573.32, and 0.56 mg·kg−1, respectively. The results of principal component analysis showed that the main heavy metal elements under the first principal component load were Cu, Ni, Zn, Mn, Cr, Pb, and Cd. The second principal component is mainly loaded with Mo, As, Hg, and Sb. The results of classified regression analysis showed that population density mainly affected Cu (0.54), soil mainly affected Ni (0.41), Sb (0.49), Zn (0.47), and Mn (0.21), and water quality mainly affected As (0.45) and Mo (0.37). Air quality mainly affected Cd (0.33) and Cr (0.37), traffic activity mainly affected Hg (0.31), and slope mainly affected Pb (0.31). The research results can be used to trace the environmental sources of soil heavy metals, fundamentally prevent and repair soil heavy metal pollution, and protect urban soil environmental quality.