Abstract

With a view to elucidating the chemistry of the benzidine-β-naphthol system, its phase diagram was determined by the thaw-melt method. The solidification behaviour of the pure components, the eutectics and the addition compound was studied at different degrees of supercooling by the capillary method. From the data obtained by X-ray diffraction, thermal and microscopic studies, it can be inferred that the eutectics are not simple mechanical mixtures of the components involved. Infrared and NMR spectral investigations were carried out to clarify the nature of bonding between the two components forming the addition compound.

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