Abstract
Both 2-chloro- and 2-fluoro[3,5- 2H 3]tropone were found to react with lithium diphenylphosphide in tetrahydrofuran to give 2-diphenylphosphino[4,6- 2H 3]tropone in what constitutes the first example of telesubstitution by an anionic nucleophile in a non-protic solvent on tropones carrying nucleofugal groups; lithium diphenylphosphide oxide showed the same behaviour.
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