Abstract
The influence of electrode on the homogeneous (chemical) electron transfer (ET) reaction occurring near it has been considered. Using the Langevin dipole (LD) method a model electron exchange reaction between a donor (aluminium atom) and an acceptor (hydroxonium cation) is investigated. The solvent (water) reorganization energies. ET activation energies and their different contributions have been calculated depending on the localization of this reaction pair regarding electrode. A catalytic effect of electrode on the ET homogeneous reaction occurring near it has been studied.
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