Abstract
Abstract The radical copolymerization of N, N-dimethylacrylamide (I) with styrene (St) (M1) was carried out in several solvents at 60 and 80°C. The monomer reactivity ratios were considerably affected by the reaction conditions. Linear correlationships were observed by plots of the values of both νC=0 and νC=C stretching frequencies of I obtained in the solvents against those of log r1, log r2, ΔΔE‡ (= ΔE11‡ - ΔE12‡), and ΔΔS‡ (= ΔS11‡ - ΔS12‡). The values of both ΔE12‡ and ΔS12‡ were also determined.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of Macromolecular Science: Part A - Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.