Abstract
The time-resolved solvation of s-tetrazine in propylene carbonate is studied by ultrafast transient hole burning. In agreement with mode-coupling theory, the temperature dependence of the average relaxation time follows a power law in which the critical temperature and exponent are the same as in other relaxation experiments. Our recent theory for solvation by mechanical relaxation provides a unified and quantitative explanation of both the subpicosecond phonon-induced relaxation and the slower structural relaxation.
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