Abstract
The time correlation function for the solvation energy fluctuation is calculated in context of a hard-sphere kinetic theory. The theory has three ingredients: a frequency measuring the thermal fluctuations in the potential, a frequency measuring the rate of passage of a solvent–solvent pair through the interaction region, and a memory function representing the longer time dynamics associated with particle recollisions. The calculated time correlation function is determined wholly in terms of hard-sphere properties, and when compared with a recent molecular dynamics simulation, the agreement is surprisingly good. The presence of fully correlated recollisions is made known by the appearance of a plateau in the time correlation function.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
