Solution combustion synthesis of MnFeCoNiCu and (MnFeCoNiCu)3O4 high entropy materials and sintering thereof

Abstract

Single-phase, fine-grained high entropy MnFeCoNiCu alloy and (MnFeCoNiCu)3O4 oxide powders have been pioneered by an in-situ solution combustion synthesis without post-treatment, utilizing alanine and glycine as organic reducers and ammonium nitrate as an auxiliary oxidizing agent. In order to regulate the porosity, homogeneity, phase composition and morphology of the obtained powders, multivariate studies on the influence of the following parameters were performed: type and quantity of reducers, pH of solution, ignition temperature, presence of oxidizing agent, etc.. It has been shown that the amount of the reducer holds the key for governing combustion temperature and speculation of lower and upper combustion limits in the systems under study. In turn, according to the temperature-time profiles of combustion, product microstructure, as well as phase composition of the product, the combustion area turned out to be divided into two sub-domains: volume combustion (with vigorous flaming) and self-propagation combustion. After thorough characterization, high entropy MnFeCoNiCu alloy and high entropy (MnFeCoNiCu)3O4 oxide powders were subjected to consolidation by spark plasma sintering and mechanical properties were evaluated. The influence of sintering temperature on the phase transformation of the products was revealed.