Abstract
The solubility parameter δ 2 and its components of broad and narrow distributed alcohol oxyethylates were determined by inverse gas chromatography. Corrected values of the solubility parameter δ T were calculated from the increments of the solubility parameter corresponding to different types of intermolecular solute-solvent interactions. The corrected value of solubility parameter is always lower than that obtained directly from Guillet and co-workers' procedure. The influence of the structure of the examined oxyethylates on the solubility parameter and its components is discussed. Narrow range distributed oxyethylates are characterized by lower values of the solubility parameters than broad range products, but the difference decreases with increase in the average oxyethylation ratio. The increase in the length of oxyethylene chain increases the solubility parameter. The solubility parameter decreases with increase in temperature. Temperature and structural dependences of the solubility parameter increments are also presented and discussed. Relationships between the solubility parameter, corrected solubility parameter, its components and polarity parameters are examined.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
