Abstract
Abstract From the temperature dependence of the solubility of tris(acetylacetonato)chromium(III) in aqueous t-butyl alcohol mixtures and in aqueous methanol mixtures, thermodynamic parameters of the solution were calculated. The solubility and these parameters in aqueous t-butyl alcohol mixtures could be explained qualitatively by the cavity formation terms of the scaled particle theory. It was suggested that tris(acetylacetonato)chromium(III) is in water microphases at XBuOH≤0.04 and in t-butyl alcohol microphases over this region.
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