Abstract

A precise knowledge of solubility of gases in liquids is essential for analyzing gas-liquid and gas-liquid-solid reactions. This paper presents solubility data of hydrogen in o-nitroanisole, o-nitroanisole-methanol mixtures, and o-anisidine under various conditions of temperature and pressure. The data are important in the design of a reactor for o-anisidine which is manufactured by catalytic hydrogenation of o-nitroanisole. No data have been published for the solubility of hydrogen in o-nitroanisole and o-anisidine. The solubility of hydrogen in o-nitroanisole, onitroanisole-methanol mixtures, and o-anisidine was studied in the range of interest for hydrogenation, namely, 40-80 /sup 0/C, 7-50 atm, and 3-8 M concentration.

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