Solubility of carbon dioxide in aqueous solution of 2-amino-2-methyl-1-propanol and piperazine

Abstract

In this work, new experimental results of the vapour–liquid equilibrium (VLE) of CO 2 in aqueous 2-amino-2-methyl-1-propanol (AMP) and piperazine (PZ) have been presented in the temperature range of 298–328 K and PZ concentration range of 2–8 mass%, keeping the total amine concentration in the solution at 30 mass%. The partial pressures of CO 2 were in the range of 0.1–1450 kPa. A thermodynamic model was developed to correlate and predict the VLE of CO 2 in aqueous AMP + PZ. The electrolyte nonrandom two liquid (ENRTL) theory has been used to develop the VLE model for the quaternary system (CO 2 + AMP + PZ + H 2O) to describe the equilibrium behaviour of the solution. The experimental data from this work and data available in the literature were used to regress the ENRTL interaction parameters. The model predictions are in good agreement with the experimental data of CO 2 solubility in aqueous blends of this work as well as those reported in the literature. The current model can also predict speciation, heat of absorption, pH of the CO 2 loaded solution, and amine volatility.