Abstract

Solubilities of CO 2 in eight hydroxyl ammonium ionic liquids 2-hydroxy ethylammonium formate (HEF), 2-hydroxy ethylammonium acetate (HEA), 2-hydroxy ethylammonium lactate (HEL), tri-(2-hydroxy ethyl)-ammonium acetate (THEAA), tri-(2-hydroxy ethyl)-ammonium lactate (THEAL), 2-(2-hydroxy ethoxy)-ammonium formate (HEAF), 2-(2-hydroxy ethoxy)-ammonium acetate (HEAA) and 2-(2-hydroxy ethoxy)-ammonium lactate (HEAL) at the temperatures ranging from 303 to 323 K and the pressures ranging from 0 to 11 MPa were determined. The solubility data were correlated using Krichevisky–Kasarnovsky equation, from which Henry's constants and the partial volumes of CO 2 at different temperature were obtained. Results showed that Krichevsky–Kasarnovsky equation can correlate the solubilities of CO 2 in these hydroxyl ammonium ionic liquids (ILs) well. Comparison showed that the solubility of CO 2 in these eight hydroxyl ammonium ionic liquids was in sequence: THEAL > HEAA > HEA > HEF > HEAL > THEAA ≈ HEL > HEAF.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call