Solar steam generation on scalable ultrathin thermoplasmonic TiN nanocavity arrays

Abstract

Plasmonic-based solar absorbers exhibit complete light absorption in a sub-µm thickness, representing an alternative to mm-thick carbon-based materials most typically employed for solar-driven steam generation. In this work, we present the scalable fabrication of ultrathin plasmonic titanium nitride (TiN) nanocavity arrays that exhibit 90% broadband solar light absorption within ~ 250 nm from the illuminated surface and show a fast non-linear increase of performance with light intensity. At 14 Suns TiN nanocavities reach ~ 15 kg h –1 m –2 evaporation rate and ~ 76% thermal efficiency, a steep increase from ~ 0.4 kg h −1 m −2 and ~ 20% under 1.4 Suns. Electromagnetic, thermal and diffusion modeling of our system reveals the contribution of each material and reactor component to heat dissipation and shows that a quasi-two-dimensional heat dissipation regime significantly accelerates water evaporation. Our approach to ultrathin plasmonic absorbers can boost the performance of devices for evaporation/desalination and holds promise for a broader range of phase separation processes. • An ultrathin solar absorber based on TiN nanocavity arrays is introduced. • The material exhibits 90% broadband solar absorption within 250 nm. • The evaporation rate and the efficiency non-linearly increase with light intensity. • An extensive multi-physics modeling supports the experimental findings. • A quasi-two dimensional heat dissipation regime is theoretically discussed.