Solar photocatalytic degradation of textile effluent with TiO2, ZnO, and Nb2O5 catalysts: assessment of photocatalytic activity and mineralization.

Abstract

The photocatalytic degradation of textile effluent was investigated using TiO2, ZnO, and Nb2O5 catalysts under solar irradiation. The procedures were carried out at ambient conditions in April 2014, with pH3.0 and catalyst concentration of 0.250gL-1. The photocatalytic activity of the oxides was evaluated by means of kinetic efficiency (rate constant and half-life time), chemical oxygen demand reduction, and absorbance reduction at 228, 254, 284, 310, 350, 500, and 660nm (λmáx). Mineralization in terms of the formation of inorganic ions and toxicity reduction using bioassays with Artemia salina were performed. TiO2 reduced the absorbance at 660nm (λmax) after 300min of solar irradiation around 94 and 93%; and 68 and 60% of COD, respectively. ZnO showed lower photocatalytic activity giving 64 and 42% of absorbance and COD reduction, respectively. The photocatalytic activity of Nb2O5 was very close to TiO2-P25. In this sense, Nb2O5 becomes a promising alternative to replace the commercial TiO2-P25. Bioassays confirmed the efficacy of treatment, increasing the lethal concentration of 27.59 (in natura) to 131.95% in the presence of Nb2O5.