Abstract

Abstract Chitin and chitosan as green and active biomacromolecules were extracted from local seafood waste (shrimp shells). The extraction was carried out by a soft chemical process, followed by structural characterization (FTIR, XRD, viscosity average molecular weight M̅v), thermal stability by TGA, and antibacterial tests. FTIR and XRD spectra confirmed the chemical structures of the extracted chitin and chitosan which were similar to the commercial ones. The chitin and chitosan had an average viscosimetric molar weight of 232.21 kDa and 41 kDa, respectively. The chitosan had a high deacetylation degree (DD = 71 %) and low cristallinity index (Icr = 68.3 %); compared to chitin, which exhibited a lower deacetylation degree (DD = 24.27 %), higher thermal stability and higher cristallinity index (Icr = 87.55 %). A bacteriostatic effect of chitin was observed in the gram-negative bacteria, Escherichia coli, Salmonella typhimurium. Chitosan exhibited a bacteriostatic effect on all bacteria tested, except Salmonella typhimurium.

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