Abstract

We present a description of the evolution of a polymorphically transforming metalnanoparticle ensemble subjected to a temperature cycling with constant rates oftemperature change. The calculations of the time dependence of the volume fraction of thenew phase show the existence of size-dependent hysteresis and its main features. Thestatistical analysis makes it possible to introduce and determine the size-dependentsuperheating limit and supercooling limit.

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