Abstract
A further insight into the photochemistry of a core excited polyatomic molecule has been obtained using a new electron-ion coincidence setup. Selecting the kinetic energy of Auger electrons in coincidence with fragment ions we observed a strong site selective fragmentation for the lowest states of the ${\mathrm{ClCH}}_{2}{\mathrm{Br}}^{2+}$ ion, following selective Br $3d$ or Cl $2p$ core photoionization. At higher energy the selectivity diminishes and is completely lost for the highest states. The pure photoselective effect has been emphasized by subtracting the thermodynamical, naturally selective, fragmentation pattern.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
