Single‐Molecule Conductance of Staffanes

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We report the first conductance measurements of [n]staffane oligomers in single‐molecule junctions. Our studies reveal two quantum transport characteristics unique to staffanes that emerge from their strained bicyclic structure. First, though staffanes are composed of weakly conjugated C‐C σ‐bonds, staffanes carry a shallower conductance decay value (β = 0.84 ± 0.02 n‐1) than alkane chain analogs (β = 0.96 ± 0.03 n‐1) when measured with the scanning tunneling microscopy break junction (STM‐BJ) technique. Staffanes are more conductive than other σ‐bonded organic backbones in the literature on a per atom basis. Density functional theory calculations suggest staffane backbones are effective conduits for charge transport because their significant bicyclic ring strain destabilizes the HOMO‐2 energy, aligning it more closely with the Fermi energy as oligomer order increases. Second, the monostaffane is significantly lower conducting than expected. DFT calculations suggest that short monostaffanes sterically enforce insulating gauche interelectrode orientations over syn orientations. Meanwhile, [2‐5]staffane wires may accommodate axial mechanical strain by “rod‐bending”. These findings show for the first time how bicyclic ring strain can enhance charge transmission in saturated molecular wires. These studies showcase the STM‐BJ technique as a valuable tool for uncovering the stereoelectronic proclivities of molecules at material interfaces.