Abstract
The first triradical bridged binuclear penta-spin single-molecule magnet, [Dy2(hfac)6(BTR)], based on a nitronyl nitroxide triradical was synthesized and characterized. Theoretical calculations revealed Dy-radical antiferromagnetic coupling and radical-radical ferromagnetic coupling. The SMM behavior is found to originate from the exchange states, rather than the isolated Dy3+ center.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have