Simultaneous spectrophotometric determination of cobalt, copper and nickel using 1-(2-thiazolylazo)-2-naphthol by chemometrics methods

Abstract

The simultaneous determination of cobalt, copper and nickel using 1-(2-thiazolylazo)-2-naphthol (first figure of this article) by spectrophotometric method is a difficult problem in analytical chemistry, due to spectral interferences. By multivariate calibration methods, such as partial least squares (PLS) regression, it is possible to obtain a model adjusted to the concentration values of the mixtures used in the calibration range. Orthogonal signal correction (OSC) is a preprocessing technique used for removing the information unrelated to the target variables based on constrained principal component analysis. OSC is a suitable preprocessing method for PLS calibration of mixtures without loss of prediction capacity using spectrophotometric method. In this study, the calibration model is based on absorption spectra in the 550–750-nm range for 21 different mixtures of cobalt, copper and nickel. Calibration matrices were formed from samples containing 0.05–1.05, 0.05–1.30 and 0.05–0.80 μg mL −1 for cobalt, copper and nickel, respectively. The root mean square error of prediction (RMSEP) for cobalt, copper and nickel with OSC and without OSC were 0.007, 0.008, 0.011 and 0.031, 0.037, 0.032 μg mL −1, respectively. This procedure allows the simultaneous determination of cobalt, copper and nickel in synthetic and real samples and good reliability of the determination was proved.