Simultaneous removal of SO2 and NO by FeII(EDTA) solution: promotion of Mn powder and mechanism of reduction

Abstract

The effect of Mn powder addition on the simultaneous removal of SO2 and NO coupled with FeII(EDTA) absorption was investigated in this work. In the NO absorption system with FeII(EDTA), SO2 reduced FeII(EDTA)-NO to FeII(EDTA) with a reduction efficiency reaching 88.5% under the conditions of 4000 mg/m3 SO2, pH 8.0, 44 °C, and the flow rate of 1.2 L/min within 60 min. Introducing 0.1 M Mn powder with SO2 increased the FeII(EDTA)-NO reduction efficiency to 96.8% within 5 min. SO2 was also removed by reducing FeII(EDTA)-NO and converted into SO42- at a removal efficiency of 100%. After adding Mn powder, NO was removed through the following reaction: [Formula: see text]. Mn powder functioned as a reductant to regenerate the absorption of solution, and the coordinated NO in FeII(EDTA)-NO was reduced to NH4+. The resource utilization rate of N reached approximately 77.2%. The integrated technology is a potential solution for flue gas treatment in industrial sectors with coal-fired power plants and industrial boiler. Graphical abstract.