Abstract

A Monte Carlo procedure is presented which allows the investigation of the relaxation process of a many-particle system from nonequilibrium states to the (thermal) equilibrium state, including chemical reactions and internal degrees of freedom. As an application the time-dependent relaxation of (a) a 100-particle system from a nonequilibrium state towards thermal equilibrium (Maxwell distribution), and (b) a chemical reacting system from a nonequilibrium state towards the chemical and thermal equilibrium state, is reproduced with this method.

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