Abstract
The modeling and simulation of the absorption of dilute CO 2 into falling film of aqueous solutions of a sterically hindered amine, 2-amino-2-methyl-1-propanol (AMP), was carried out using COMSOL Multiphysics Version 3.3. The operating cases were divided in gas turbine cases (CO 2 3 mol%) and boiler cases (CO 2 8.5 mol%). The key operating parameters for the studied cases are CO 2 partial pressure, operating temperature and amine concentration in the aqueous solution. The simulation focused on: (1) CO 2 loading in aqueous AMP solution; (2) contact time to reach equilibrium; (3) pH of rich AMP aqueous solution; and (4) total required interfacial area/circulated AMP aqueous solution. The modeling was validated by comparison with experimental results for CO 2 loading available in the literature, with deviations below 4%. High operating pressure, low operating temperature, and low AMP aqueous concentration increase CO 2 loading. The compression need for gas turbine flue gas was found to be higher than for boiler flue gas. The pH of rich AMP aqueous solution at maximum CO 2 loading was 8. The needed contact time to reach equilibrium decreases with temperature increases. The results were utilized to estimate the lower bound to the size of structured packed columns to absorb CO 2 from flue gases.
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