Simple and low-cost anion exchange membrane based on PVA and PDC for acid recovery by diffusion dialysis

Abstract

Anion exchange membranes were prepared by a simple method on the basis of polyvinyl alcohol (PVA) and 1,4-Piperazinedicarboxaldehyde (PDC). A network structure was formed in the membranes by cross-linking between PVA and PDC. The mechanical stability and acid stability the prepared membranes was tested. The TS value was tested as 17.5–37.8 MPa, Eb was 120.4–54.7% and the mass retention in the acid environment was 98.4–97.2%. Meanwhile, the physicochemical properties of membranes, such as thermogravimetric analysis (TGA), water absorption (WR), ion exchange capacity (IEC) and linear expansion rate (LER). WR was 106.9–136.7%, IEC was 1.03–1.55 mmol/g, and LER was 37.93–33.33%. In practical application, diffusion dialysis (DD) performance of membranes were tested. In DD test, the acid dialysis coefficient (UH+) was 17.5–27.9 × 10−3 m/h, and the separation factor (S) was 31.25–23.38. The UH+ and S were all higher than commercial membrane DF-120 (UH+ is 9 × 10−3 m/h and S is 18.00). Results were shown that the comprehensive properties of membranes were good. Therefore, the prepared membranes had broad application prospects for acid recovery by diffusion dialysis.