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PDF Availablehttps://doi.org/10.1021/acs.orglett.7b03142
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Cite Journal: Organic letters |  Publication Date: Nov 9, 2017 |
 Citations: 7 |
Affiliation: University of Pennsylvania
Lynchpins comprising α-silyl amides have been validated for type I anion relay chemistry (ARC) to permit ready access to γ-ketoamides. Importantly, the ARC protocol can be run at ambient temperature without the need of additional reagents to trigger the [1,4] Brook rearrangement.
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