Significant enhancement of luminescence properties of YAG:Ce ceramics by differential grain sizes control

Abstract

High-brightness laser lighting requires high luminous efficacy and high thermal performance of luminescent materials. In this study, we designed and fabricated single-phase YAG:Ce ceramics with differential grain sizes by combining the coarse commercial phosphor and fine powder of precusor. The large YAG:Ce grains mainly contribute to excellent luminescence properties. The small YAG:Ce grains not only change the direction of light propagation to improve the luminous efficiency but also effectively increase the Ce3+ content to improve the absorption of blue light, which significantly further enhance the luminescence properties compared with the second phase in the YAG:Ce-base composite ceramics. The luminescent ceramic with 40 wt% large grains sintered under 1550 °C has the highest luminous efficacy of 398.5 lm/W. Compared with the Al2O3–YAG:Ce composite ceramic, the single-phase YAG:Ce ceramic effectively increased the absorption of blue light to enhance the luminescence properties without the adverse effects caused by the transverse scattering of light in the Al2O3 phase. After encapsulating the ceramic onto a radiator, a high luminous flux of 7697.6 lm under the blue-laser excitation of 3.0 A (54.6 W) was obtained. These indicated its broad application prospects in high-power solid-state laser lighting.