Sigma phases in an 11%Cr ferritic/martensitic steel with the normalized and tempered condition

Abstract

At the present time 9–12% Cr ferritic/martensitic (F/M) steels with target operating temperatures up to 650°C and higher are being developed in order to further increase thermal efficiency so as to reduce coal consumption and air pollution. An 11% Cr F/M steel was prepared by reference to the nominal chemical composition of SAVE12 steel with an expected maximum use temperature of 650°C. The precipitate phases of the 11% Cr F/M steel normalized at 1050°C for 0.5h and tempered at 780°C for 1.5h were investigated by transmission electron microscopy. Except for Cr-/Cr-Fe-Co-rich M23C6, Nb-/V-/Ta-Nb-/Nd-rich MX, Fe-rich M5C2, Co-rich M3C and Fe-Co-rich M6C phases previously identified in the steel, two types of sigma phases consisting of σ-FeCr and σ-FeCrW were found to be also present in the normalized and tempered steel. Identified σ-FeCr and σ-FeCrW phases have a simple tetragonal crystal structure with estimated lattice parameters a/c=0.8713/0.4986 and 0.9119/0.5053nm, respectively. The compositions in atomic pct of the observed sigma phases were determined to be approximately 50Fe-50Cr for the σ-FeCr, and 30Fe-55Cr-10W in addition to a small amount of Ta, Co and Mn for the σ-FeCrW. The sigma phases in the steel exhibit various blocky morphologies, and appear to have a smaller amount compared with the dominant phases Cr-rich M23C6 and Nb-/V-/Ta-Nb-rich MX of the steel. The σ-FeCr phase in the steel was found to precipitate at δ-ferrite/martensite boundaries, suggesting that δ-ferrite may rapidly induce the formation of sigma phase at δ-ferrite/martensite boundaries in high Cr F/M steels containing δ-ferrite. The formation mechanism of sigma phases in the steel is also discussed in terms of the presence of δ-ferrite, M23C6 precipitation, precipitation/dissolution of M2X, and steel composition.