Abstract

AbstractThe synthesis of a new side‐chain polyrotaxane containing β‐dimethyl cyclodextrin rings is described. The rotaxane side groups are attached via amide functions at an aromatic polysulfone. Some characteristics of the polyrotaxane are compared with those of a corresponding guest model compound. It is found that the Tg value, the solubility in chloroform and acetone, some 1H‐NMR shifts and the GPC maximum are significantly influenced by the non‐covalently anchored cyclodextrin rings.

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