Si Heterojunction Solar Cells: A Simulation Study of the Design Issues

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Silicon heterojunction solar cells having semiconducting oxide-selective contacts can revolutionize the photovoltaic industry with the promise of low cost and high efficiency. In this paper, we have identified the potential design issues of silicon heterojunction cell using simulation. This paper compares two possible electron-selective oxides (TiO2 and ZnO) and two possible hole-selective oxides (CuAlO2 and NiO). The Fermi level in the oxide at the oxide/metal interface is pinned by the metal (its workfunction and eventual interface dipoles). We considered this effect, which determines the effective workfunction of the metal contact as opposed to the actual metal workfunction. Our simulation suggests that Fermi level pinning has significant impact on the device performance. We also considered different interface passivation effects and oxide dopings in our simulation. The simulation suggests that high doping in oxides is beneficial to counter balance the effect of poor surface passivation. This paper provides an extensive understanding of the design of Si heterojunction solar cell using band-engineered semiconducting oxide as the selective contact replacing highly doped emitter and back surface field.