Abstract

We theoretically show that the process of inner-shell photoionization in an atom A, followed by the spontaneous sequential emission of two Auger electrons, produces various kinds of spin-entangled states of three flying electronic qubits. All properties of these states are completely pre-determined by the total spin quantum numbers of the electronic states of four atomic species (i.e., A, A + ∗ , A 2 + ∗ , A 3 + ) participating in this process in the Russell–Saunders coupling. These tripartite states are readily characterized experimentally by measuring only energies of the three emitted electrons, without requiring any entanglement witness or other such protocols.

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