Abstract

The forces influencing the separation order of monosubstituted benzonitriles on 1,2,3-tris-(2-cyanoethoxypropane), poly(propyleneglycol), dinonyl phthalate, tritolyl phosphate, 2,4,7-trinitrofluorenone, silicone oil and silicone gum rubber are discussed. Specific retention volumes, heats of solution, electron polarizabilities and dipole moments were calculated. 1,2,3-Tris-(2-cyanoethoxypropane) was found to be selective for the quantiative separation of the isomers studied, followed by dinonyl phthalate, poly(propylene glycol) and tritolyl phosphate.

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