Abstract
α-Hydroxyisobutyronitrile (acetone cyanohydrin, ACH) reacts with metals in ammoniacal medium and yields cyano complexes of negative charge. On this basis, Ni 2+, Cu 2+, Hg 2+, Zn 2+, Cd 2+ and Fe 2+ can be separated on a strongly basic anion exchanger in the chloride form as cyano complexes from Mg 2+, Ba 2+, Ca 2+, Na + and K +. The structure of complexes were examined on a strongly basic anion exchanger in the Cl − form and on a strongly acidic cation exchanger in the H + form. In slightly ammoniacal medium, Cu(CN) 4, Co(CN) 3.6 and Ni(CN) 3.2 were found. The complex adsorbs on the anion exchanger in the Cl − form as a divalent [NH 4Cu(CN) 4] 2− or a monovalent [NH 4Zn(CH) 4] − complex ion.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
