Separation characteristics of low-temperature coal tar containing solid particles by vacuum distillation: Effects of distillation pressure and solid particle content

Abstract

The separation of low-temperature coal tar (LTCT) containing solid particles by vacuum distillation is essential in various applications, such as in-situ pyrolysis. However, the separation characteristics of solid-containing LTCT using vacuum distillation have yet to be fully understood. Therefore, explorations were conducted with variations in pressure and solid particle concentration by analyzing pitch with Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The FTIR demonstrated that the organic constituents exhibit greater regularity at higher temperatures, leading to a 2 % reduction in the tightly bound cyclic OH tetramers, an intricate hydrogen bonding. The structural parameters indicate a 2 % decrease in farH, alongside a decline in AR from 0.332 to 0.293. This suggests that the low-pressure distillation conditions contribute to an increased retention of aromatic hydrocarbons in pitch, potentially complicating its subsequent utilization. The reduction in F from 2.273 to 2.029 signifies a shorter aliphatic chain, indicative of an intensified degradation effect. The elevated content of solid particles results in a more rigid texture of pitch in micromorphology. This study examined LTCT pitch to clarify the separation mechanism of solid-containing LTCT, offering insights into appropriate vacuum distillation conditions for LTCT separation and aiding in the effective utilization of pitch products.