Semiconductor Quantum Dots Act as Photocatalysts for Carbon-Carbon Bond Formation: Selective Functionalization of Xanthene's 9H Position.

Abstract

The potential of CdSe, CdS, MoS2, and WS2 QDs as semiconductor photocatalysts for selective functionalization of the xanthene 9H position through carbon-carbon bond formation has been investigated. Our study reveals valuable insights into the energy-transfer and electron-transfer pathways involved in these reactions, as well as the radical polar crossover (RPC) and triplet-to-triplet energy transfer (TTEnT) processes. Notably, this approach offers a range of intriguing features, including visible-light-mediated processes, inexpensive catalytic systems, mild reaction conditions, broad substrate scope, unfunctionalized starting materials, and suitability for gram-scale synthesis. This study makes a significant contribution to the newly emerging field of QD-catalyzed reactions, paving the way for future explorations.