Abstract

In this paper, the semiconducting behavior of non-solid electrochemical state of carbon steel in acid, base and salt solutions was studied by utilizing potential-capacitance and Mott-Schottky analysis. It was pointed out that the capacitance variation of space charge layer of non-solid electrochemical state of carbon steel in different solution was different. The non-solid electrochemical state showed p-type semiconducting behavior in 5 sulfuric acid and 5 % sodium sulfate solution. However, it showed n-type semiconducting behavior in 5 % sodium hydroxide, suggesting that the space charge layer of non-solid electrochemical state of the carbon steel in different electrolytes might be asymmetric.

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